| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 73716 | Microporous and Mesoporous Materials | 2013 | 6 Pages |
A zeolite beta–silicalite-1 composite was prepared by growing polycrystalline silicalite-1 shells on single micron-sized zeolite beta crystals. The obtained core–shell material was employed for the separation of hexane isomers. Gravimetric uptake measurements revealed that the silicalite-1 shell acted as a membrane that controlled the transport to zeolite beta core. The positive impact of the silicalite-1 membrane on the separation of mono- and di-branched hexane isomers was confirmed by breakthrough experiments. The core–shell composite material allowed more selective separation of mono- and di-branched isomers than either of its components alone and had a significantly higher adsorption capacity than silicalite-1.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► The separation of mono- and di-branched hexane isomers was tested on the core–shell composite. ► The silicalite-1 shell plays the role of a membrane controlling the access to the beta core. ► The mono/di selectivity of the composite is higher than that of the silicalite-1 reference sample.
