| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 73730 | Microporous and Mesoporous Materials | 2013 | 8 Pages |
In this paper, a study on direct growth of SAPO (CHA) zeolites on aluminium foamed supports is presented. A preliminary investigation on SAPO-34 and SAPO-44 syntheses was carried out by conventional hydrothermal and microwave route to select appropriate formulations for in situ growth on aluminium foams. Adsorption capacity of coated foams were evaluated by a McBain system and compared to adsorption isobars of pure zeolites measured by a Chan microbalance. Coated samples showed the typical behaviour of the corresponding zeolite, confirming that the interaction with aluminium support was not detrimental to the zeolite adsorption performances. SAPO-34 coatings grew ten times faster by microwaves than by hydrothermal route, while for SAPO-44 the microwave deposition was not feasible for the intense corrosion of aluminium foams.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► SAPO 34 and SAPO 44 zeolites have been prepared by standard hydrothermal and microwave synthesis. ► Coatings of the two zeolites have been obtained on aluminium foams by in situ synthesis. ► The in situ growth has been achieved by standard hydrothermal and microwave synthesis. ► Water adsorption values of zeolite coatings have been measured and compared to pure zeolites.
