Article ID Journal Published Year Pages File Type
73809 Microporous and Mesoporous Materials 2013 4 Pages PDF
Abstract

MOF-5 and ZIF-8 were used for the first time as matrices for pigments containing entrapped dmit. The chromophore was introduced either by impregnation or by its synthesis from CS2 inside the matrices. Pigments with ZIF-8 resisted washing and maintained the structure, while these with MOF-5 underwent structure altering or amorphization.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► The ZIF-8, MOF-5 appeared efficient matrices for stable dmit pigments. ► Entrapping of dmit can be attained either by impregnation or by synthesis of dye inside MOF voids. ► Probably dmit molecules form bulky complexes with structural Zn cations. ► ZIF-8 structure is not affected, while MOF-5 undergoes some transformation on pigment synthesis.

Related Topics
Physical Sciences and Engineering Chemical Engineering Catalysis
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