CO detection in H2 reducing atmosphere with mini fuel cell

A prototype of a miniaturized fuel cell has been studied in order to detect carbon monoxide in hydrogen-rich atmosphere for PEMFC (proton exchange membrane fuel cell) applications. It consists on a single PEMFC (membrane-electrode-assembly supplied by CEA/LITEN) directly fed by the hydrogen–carbon monoxide mixture while the cathode is exposed to ambient air. Experiments have been carried out on a laboratory testing bench with simulated reforming gas. Two working modes have been studied. For low CO concentrations (≤20 ppm), the amperometric mode is suitable but a regeneration in air is necessary to obtain a good reversibility of the sensor response. On the contrary, for higher CO concentrations (250–4000 ppm), a good reversible response is observed without air regenerating by using a potentiometric or quasi-potentiometric mode. Therefore, this prototype of mini fuel cell sensor seems to be convenient for monitoring reformed gases either for low temperature PEMFC which are poisoned by very low traces of CO or for high temperature PEMFC which can operate at higher CO concentrations.