Article ID Journal Published Year Pages File Type
74143 Microporous and Mesoporous Materials 2012 8 Pages PDF
Abstract

A sulfide-selective electrode based on surfactant modified zeolite (SMZ) particles into PVC membrane has been proposed (SMZ-PVC). The electrode was exhibited linear response range to sulfide in the range of 1.0 × 10 −7 to 1.0 × 10−1 mol L−1 with detection limit of 6.3 × 10−8 mol L−1 and Nernstian slope of 29.4 ± 0.8 mV per decade of sulfide concentration. The successful determination of sulfide in real sample of a sugar company waste sample, using direct potentiometry is presented.

Graphical abstractA sulfide-selective electrode based on surfactant modified zeolite (SMZ) particles into PVC membrane has been proposed (SMZ-PVC). The electrode was exhibited linear response range to sulfide in the range of 1.0 × 10−7 to 1.0 × 10−1 mol L−1 with detection limit of 6.3 × 10−8 mol L−1 and Nernstian slope of 29.4 ± 0.8 mV per decade of sulfide concentration. The successful determination of sulfide in real sample of a sugar company waste sample, using direct potentiometry is presented.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Surfactant modified zeolite in PVC membrane electrode can respond to anions. ► The obtained SMZ–PVC membrane electrode showed a Nernstian response to sulfide in the used conditions. ► The proposed method cab be used in direct and indirect potentiometry and real samples.

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Physical Sciences and Engineering Chemical Engineering Catalysis
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