Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
74446 | Microporous and Mesoporous Materials | 2012 | 7 Pages |
In this paper, for the first time, Ni/Al layered double hydroxides (LDHs) with high specific surface area and high porosity were developed via a facile and environmentally friendly solvothermal approach. The obtained Ni/Al LDHs have a diameter of 1–10 μm, which are self-assembled by 15 nm-sized primary particles and 200 nm size secondary particles. The BET surface area of the sample is determined to about 300 m2 g−1, which is about three times than that prepared by conventional hydrothermal route. The average pore size is 3.97 nm. Notedly, the specific capacitance of this hierarchical porous Ni/Al LDHs reaches 477 F g−1 at a current density of 2.5 A g−1, which is nearly double that of Ni/Al LDHs synthesized by conventional hydrothermal procedure. The capacitance loss is less than 5% after 400 charge–discharge cycles, suggesting the high potential as electrode materials in electrochemical capacitors. The formation mechanism of self-assembled hierarchical porous Ni/Al LDHs through solvothermal method was also proposed.
Graphical abstractSelf-assemble of Ni/Al layered double hydroxides (LDHs) with high specific surface area and high porosity via a facile and environmentally friendly solvothermal approach.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Self-assembled hierarchical porous layered double hydroxides by a facile and environmentally friendly solvothermal approach. ► High surface area and high porosity make LDHs display better electrochemical performance. ► A possible growth mechanism to explain the hierarchical structure is proposed.