Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
745497 | Sensors and Actuators B: Chemical | 2012 | 6 Pages |
Abstract
Anionic water-soluble polyfluorene (PBPSO3Na) and cationic boronic acid functional viologens (BBVs) were synthesized and combined into three new two-component chemosensors of d-monosaccharides, respectively. The sensing abilities of the three chemosensors for detection of d-monosaccharides were determined by fluorescence in a pH 7.4 buffer solution. The results show that o-BBV/PBPSO3Na and m-BBV/PBPSO3Na ensembles both have high selectivity and sensitivity for d-fructose with reversible “on–off” fluorescence responses. Due to different substituted positions of boronic acid groups in BBVs and electrostatic interactions of three BBVs with PBPSO3Na, the sensing order to d-fructose is m-BBV/PBPSO3Na > o-BBV/PBPSO3Na > p-BBV/PBPSO3Na.
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
Xiaoju Wang, Guofeng Wang, Fei Liang, Yue Wang, Xing Wei, Liheng Feng, Liwei Zhang,