Article ID Journal Published Year Pages File Type
746030 Sensors and Actuators B: Chemical 2007 7 Pages PDF
Abstract

An oxovanadium-salen complex (N,N′-ethylene-bis(salicylideneiminato) oxovanadium) thin film deposited on a graphite–polyurethane electrode was investigated with regard to its potential use for detection of l-dopa in flow injection system. The oxovanadium(IV)/oxovanadium(V) redox couple of the modified electrode was found to mediate the l-dopa oxidation before its use in the FIA system. Experimental parameters, such as pH of the carrier solution, flow rate, sample volume injection and probable interferents were investigated. Under the optimized FIA conditions, the amperometric signal was linearly dependent on the l-dopa concentration over the range 1.0 × 10−6 to 1.0 × 10−4 mol L−1 (Ianodic μA) = 0.01 + 0.25 [l-dopa μmol L−1]) with a detection limit (S/N = 3) of 8.0 × 10−7 mol L−1 and a sampling frequency of 90 h−1 was achieved. For a concentration of 1.0 × 10−5 mol L−1l-dopa, the R.S.D. of nine consecutive measurements was 3.7%.

Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
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