Article ID Journal Published Year Pages File Type
74656 Microporous and Mesoporous Materials 2011 9 Pages PDF
Abstract

Treatment of the zeolitic layered precursor of Al-MWW, so-called Al-MWW(P), with diethoxydimethylsilane (DEDMS) in 1.0 M HNO3 media gave an aluminosilicate-type interlayer-expanded zeolite MWW (Al-IEZ-MWW) with expanded 12-membered ring (12-MR) micropores. By the interlayer-silylation of Al-MWW(P), the micropore diameter of interlayers with 12-MR supercages enlarged from ca. 7.0 to ca. 8.0 Å, verifying the formation of the interlayer-expanded structure. The interlayer-silylation of Al-MWW(P) under the acidic conditions with 1.0 M HNO3 caused the penetration of DEDMS molecules into the interlayers, resulting in the formation of monomeric silica puncheons between the MWW layers. Whereas the interlayer-silylation of Al-MWW(P) by using 1.0 M HNO3 caused remarkable dealumination of the MWW framework, the “two-step” silylation, namely, the first silylation in 0.1 M HNO3 and the following silylation in 1.0 M NH3, gave Al-IEZ-MWW retaining most of framework Al. The obtained Al-IEZ-MWW showed a high catalytic activity in the Friedel–Crafts acylation of anisole with acetic anhydride compared to Al-MWW as well as zeolite beta, suggesting that Al-IEZ-MWW is a useful candidate as a solid acid catalyst for the acylation reactions and other acid-catalyzed reaction of bulky molecules.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► The interlayer silylation of Al-MWW layered precursor gave Al-IEZ-MWW with 12-MR. ► The “two-step” silylation gave Al-IEZ-MWW retaining most of framework Al. ► The Al-IEZ-MWW showed high catalytic activity in Friedel–Crafts acylation of anisole.

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Physical Sciences and Engineering Chemical Engineering Catalysis
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