Article ID Journal Published Year Pages File Type
747272 Sensors and Actuators B: Chemical 2006 11 Pages PDF
Abstract

Intrinsic waveguide optical sensors, IWOS, formed by an exposed core (modified in some cases with a material sensitive to a target parameter), in contact with a measured fluid, have diverse applications. We have identified a novel referencing method for this type of sensor. The referencing method is a self-calibrating procedure that allows for development of portable sensors capable of continuous monitoring. This paper examines the theoretical basis of the proposed referencing method and constitutes a first step in the practical design of such optical sensors. Since the most commonly measured parameter with such sensors is the real term (n) of the complex refractive indices (m = n + ki), real index of refraction for different fluids and glass waveguide materials are used to investigate sensor responses. Case studies, in which ncore > nmeasured fluid and ncore < nmeasured fluid are considered, suggest that an easily configurable optical photo-refractometer can be designed with a variable dynamic range. This means that IWOS physicochemical detection characteristics (extent of reaction, species concentrations, etc.) can be usefully related to refractive index variations through self-calibrating strategies. It is also shown that portable spectrophotometers allow for measurement of spectral signals that are diagnostic of the measured material.

Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
Authors
, , ,