| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 75194 | Microporous and Mesoporous Materials | 2010 | 9 Pages |
Cobalt and/оr iron modified Ti-MCM-41 materials, prepared by an incipient wetness impregnation technique, were investigated using X-ray diffraction (XRD), N2 physisorption, temperature-programmed reduction (TPR-TGA), FT-IR spectroscopy, EPR and Mössbauer spectroscopy. Formation of finely dispersed metal oxide species could be observed for the cobalt and/or iron modified Ti-MCM-41 samples. The surface properties of the mesoporous support and the pretreatment procedure (media and temperature) predetermine the types of the formed metal oxides, their dispersion, reducibility and the catalytic activity in total oxidation of toluene. It was also found that incorporation of lower amount of titanium into the mesoporous support favors the formation of finely dispersed iron or/and cobalt ions on Fe/Ti-MCM-41 and CoFe/Ti-MCM-41 samples. The high and stable catalytic activity of Co/Ti-MCM-41 samples was due to the formation of finely dispersed Co3O4 nanoparticles. Cobalt oxide with optimal dispersion could be obtained by pretreatment in air and subsequently in hydrogen at 773 K. This effect was more pronounced for Co/Ti-MCM-41 catalyst with higher titanium content (Si/Ti = 10). Formation of finely dispersed cobalt ferrite particles in CoFe/Ti-MCM-41 samples following pretreatment in air and subsequently in hydrogen at 773 K had an additional positive effect on the catalytic performance.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideResearch highlights► Iron and/or cobalt oxide impregnated Ti-MCM-41 materials are stable and highly active catalysts for total oxidation of VOCs (toluene). ► Catalytic activity strongly depends on the pretreatment procedure of the catalyst. ► Optimal dispersion of cobalt oxide particles can be obtained by pretreatment in air and subsequently in hydrogen at 773 K. ► Formation of Fe2CoO4 spinel phase in bi-component catalyst facilitates the catalytic activity.
