Article ID Journal Published Year Pages File Type
76113 Microporous and Mesoporous Materials 2008 8 Pages PDF
Abstract

This paper presents a method for the preparation of magnetic hollow ZSM-5/Ni composite spheres. ZSM-5/Ni/PS spheres were firstly synthesized by assembling ZSM-5 nanoparticles on the surfaces of Ni/PS spheres, followed by hydrothermal treatment to form a compact ZSM-5 layer. Magnetic hollow ZSM-5/Ni spheres were subsequently obtained by calcination and reduction of the ZSM-5/Ni/PS spheres. The samples were characterized by scanning electron microscope (SEM), X-ray diffraction (XRD), thermogravimetry (TG), energy dispersive X-ray spectroscopy (EDX), temperature-programmed reduction (TPR) and a vibrating sample magnetometer (VSM). A continuous ZSM-5 layer with a thickness of 400 nm was formed on the surface of Ni/PS spheres after one cycle of adsorption of ZSM-5 nanoparticles and hydrothermal treatment at 80 °C for 36 h. By changing the hydrothermal treatment time, the thickness of zeolite layer can be controlled. The hollow ZSM-5/Ni spheres inherited magnetic property from the nickel layer and their magnetization value could be adjusted by varying the thickness of the nickel layers.

Related Topics
Physical Sciences and Engineering Chemical Engineering Catalysis
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