Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
76253 | Microporous and Mesoporous Materials | 2007 | 7 Pages |
Abstract
The rational synthesis of open-framework materials with extra-large micropores is a challenging topic in the field of zeolites science. Employing computational methods, the charge-density matching, space matching, and non-bonding interactions of the host framework and guest template molecules have been studied for some known microporous materials with 14-, 16-, 18-, 20- and 24-ring extra-large micropores. The host–guest relationship in different synthetic systems has been summarized. This study provides a useful guidance for rational choice of templates for the synthesis of extra-large microporous materials with predetermined structures and compositions.
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Jiyang Li, Jihong Yu, Ruren Xu,