Article ID Journal Published Year Pages File Type
76281 Microporous and Mesoporous Materials 2007 11 Pages PDF
Abstract

The dependence of the structural properties of mesoporous aluminosilicate nanoparticles on preparative parameters were thoroughly investigated in a binary surfactant system composed of cetyltrimethylammonium bromide and polyethylene glycol (PEG-4000). Structural control could be achieved by adjusting the parameters for the hydrolysis of silica precursor which was induced by acidic aluminum salt and the subsequent assembly of hydrolyzed species with surfactants under basic conditions. The formation of the mesoporous aluminosilicate nanoparticles was based on the balance between the ordered assembly of anionic inorganic species and cationic micelles through electrostatic interaction and the regulation of grain size distribution through hydrogen bonds with nonionic PEG-4000 surrounding the nanoparticles.

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Physical Sciences and Engineering Chemical Engineering Catalysis
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