Characterization of mesoporous alumina prepared by surface alumination of SBA-15

Mesoporous aluminas of controlled pore sizes were synthesized by multiple grafting of Al isopropoxide in organic solvents on mesoporous silica SBA-15. These materials were characterized by N2 physisorption, TEM, XRD, 27Al NMR and their surface chemical properties were probed by DRIFT, cumene cracking and MoO3 thermal spreading. The results show that the chemical nature of the Al-grafted materials varies continuously with the number of grafting from pure silica to pure alumina. Typically, after three graftings, this original method of synthesis allows one to prepare ordered mesoporous aluminas with specific surface areas above 300 m2 g−1 and a narrow pore size distribution centered on ca. 60 Å. In addition to the characterizations, different models were developed to understand the evolution of the specific surface area and to discard a possible pore blocking.