Article ID Journal Published Year Pages File Type
76484 Microporous and Mesoporous Materials 2009 7 Pages PDF
Abstract

A series of layered compounds of zirconium glyphosate and zirconium phosphate–glyphosates were synthesized with ZrOCl2, N-(phosphonomethyl)glycine and H3PO4 for the first time. It was found that the morphologies of zirconium phosphate–glyphosates had a strong variational rule from hexagon to sphere and sphere to lamella when nH3PO4/nGlyphosatenH3PO4/nGlyphosate changed from ∞ to 0, and also it was found that the product of zirconium glyphosate could be decomposed gradually in basic condition with pH value of lye increased. A monochromatic body of ZrGPEu under illumination of UV light was obtained by Eu3+ exchanged and coordinated with imido and carbonyl groups in the gallery of the layers.

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Physical Sciences and Engineering Chemical Engineering Catalysis
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