Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7705301 | International Journal of Hydrogen Energy | 2018 | 8 Pages |
Abstract
Pt-M alloy nanoparticles (NPs) with well-defined size and compositions exhibit dramatically catalytic performance in chemical reactions. In this work, monodisperse PtCu NPs with controlled size and compositions were synthesized by the co-reduction method in the presence of oleylamine. These NPs have excellent catalytic activities in the hydrolytic dehydrogenation of ammonia borane (AB) and their activities were composition dependent. Among the different-composition PtCu NPs, the Cu50Pt50 NPs exhibit the highest catalytic activity with an initial turnover frequency of 102.5 mol(hydrogen)·mol(catalyst)â1·minâ1 and an apparent activation energy of 36 kJ·molâ1, which demonstrate the validity of partly replacing Pt by a first-row transition metal on constructing high performance heterogeneous nanocatalysts for the hydrolytic dehydrogenation of AB.
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Authors
Manyi Gao, Weiwei Yang, Yongsheng Yu,