Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7706111 | International Journal of Hydrogen Energy | 2018 | 8 Pages |
Abstract
High porosity nitrogen and phosphorous co-doped carbon nanosheets with high surface area (1057.9Â m2Â gâ1) are fabricated by using polyacrylonitrile and red phosphorous as the precursors. The catalyst exhibits outstanding catalytic performance towards oxygen reduction reaction (ORR), with its half-wave potential 35Â mV more superior to that of Pt/C. In addition to high ORR performance, our catalyst also exhibits remarkable methanol tolerance, outstanding stability, as well as high catalytic efficiency (almost 100% selectivity towards four-electron path). Based on the characterization results, we find that moderate P introduction can significantly modify catalysts N compositions, as well as porous structures, which, we suggest, should be the proper origins to our catalyst's outstanding performance.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Electrochemistry
Authors
Chenghang You, Lili Wang, Yanxia Huang, Xiaowei Jiang, Xiaobao Li, Chongtai Wang, Yingjie Hua, Xianghui Wang, Shijun Liao,