Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7707690 | International Journal of Hydrogen Energy | 2018 | 9 Pages |
Abstract
The elastic and electronic properties of a series of bialkali alanates M2Mâ²AlH6 (Na2LiAlH6, K2LiAlH6, K2NaAlH6) have been investigated by first principles calculations. The calculated lattice parameters and decomposition enthalpies are in good agreement with the experimental and other available data. All M2Mâ²AlH6 hydrides are found to be mechanically stable and brittle. The elastic moduli, Vickers hardness and the Debye temperature follow the order of Na2LiAlH6Â >Â K2LiAlH6Â >Â K2NaAlH6. The calculated elastic anisotropy indexes AZ, AU, AE indicate that the M2Mâ²AlH6 hydrides exhibit obvious anisotropy and the sequence follows K2LiAlH6Â >Â K2NaAlH6Â >Â Na2LiAlH6. From the density of states, the crystal orbital Hamiltonian population, bonding charge density, electron localization function and the Bader charge analyses, it can be confirmed that the existence of polar covalent bonding between Al and H within the [AlH6]3â units and ionic bonding between [AlH6]3â units and M, Mâ².
Related Topics
Physical Sciences and Engineering
Chemistry
Electrochemistry
Authors
Rong-Kai Pan, Jian-Gang Yao, Ren-Long Ji, Wen-Wen Liu, Deng-Feng Yin,