Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7709428 | International Journal of Hydrogen Energy | 2017 | 8 Pages |
Abstract
In this paper, we present a straightforward synthesis of bimetallic radical scavengers supported onto silica and an evaluation of their effectiveness to increasing the lifetime of Aquivion® PFSA membranes. Such scavengers comprise cerium (Ce) and chromium (Cr) and were incorporated in e-PTFE reinforced thin membranes through suspension in water-based Aquivion® PFSA dispersion. The bimetallic samples were physico-chemically characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM) and Energy Dispersive X-ray (EDX) analyses and compared to the monometallic Ce and Cr scavengers prepared in the same way. The membranes containing the mono- or bi-metallic scavengers were electrochemically investigated in terms of polarization behavior, cell resistance and durability. The MEA based on monometallic Ce-based scavenger showed the largest durability (7-time more than a reference MEA). The bimetallic scavenger appears also very promising. However, a proper optimization of the composition is required for its application in highly durable composite Aquivion® membrane.
Related Topics
Physical Sciences and Engineering
Chemistry
Electrochemistry
Authors
C. D'Urso, C. Oldani, V. Baglio, L. Merlo, A.S. Aricò,