Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7712423 | International Journal of Hydrogen Energy | 2016 | 9 Pages |
Abstract
In this work a high temperature polymer electrolyte fuel cell based on a phosphoric acid doped polybenzimidazole membrane is operated at 160 °C on dry air and dry hydrogen. The anodic stoichiometry was varied to resemble typical operation with pure hydrogen or reformate gas. At the outlet of the fuel cell liquid water was collected by condensers. The resulting amounts of liquid water from cathode and anode were computationally analyzed. The results yielded an effective diffusion coefficient of water vapor of Dâ2.7â
10â7Â m2Â sâ1, which is the average value for the cell based on the water partial pressures at the outlets. From the calculated water partial pressures at the anode and cathode it can be concluded that the concentration of phosphoric acid differs significantly within catalyst layer of the anode and cathode. Finally, the crossover of hydrogen and oxygen was shown to depend on the swelling of the membrane.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Electrochemistry
Authors
Uwe Reimer, Jannik Ehlert, Holger JanÃen, Werner Lehnert,