Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7715949 | International Journal of Hydrogen Energy | 2015 | 6 Pages |
Abstract
Shaping of Zr-MOF powder material into spherical pellets with diameters of 0.5-15Â mm in the presence of 10Â wt.% sucrose as a binder was successfully demonstrated using a granulator. Zr-MOF pellets were produced in a kilogram batch within 30Â min operation time. This granulation approach is a more efficient way to shape MOF-type powder materials into application-specific configurations compared to the mechanical pressing method. The pellets could be conveniently packed in a small hydrogen storage tank. The physical degradation characteristics of the Zr-MOF pellets were studied by drop test and simulated tumbler drum test. The results showed zero breakage of the pellets after 70 consecutive drops at a height of 0.5Â m and 5% breakage after 60Â min of tumbling time at a speed of 25Â rpm. Although the compromised value of the surface area led to a decreased hydrogen storage capacity, this shaping approach still holds promise given an appropriate choice of binder.
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Authors
Jianwei Ren, Nicholas M. Musyoka, Henrietta W. Langmi, Ashton Swartbooi, Brian C. North, Mkhulu Mathe,