Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7718637 | International Journal of Hydrogen Energy | 2014 | 5 Pages |
Abstract
Novel composite materials based on La0.9Sr0.1Ga0.8Mg0.2O2.85 (LSGM) and a binary eutectic carbonates (52 mol% Li2CO3:48 mol% Na2CO3) are potential electrolytes for low-temperature solid oxide fuel cells (LTSOFCs) operating at 400-600 °C. However, thermal stability of the LSGM-(Li/Na)2CO3 composites remains in doubt due to the molten state of the carbonates at elevated temperature. In this paper, XRD, SEM, TGA and EIS were employed for thermal ageing and cycling studies of the LSGM-(Li/Na)2CO3 composites. XRD and SEM results showed that ageing induced a slight effect on the structure and morphology of the composites. TGA and EIS results indicated that the composites had a good stability during cycling. The LSGM-20 wt% (Li/Na)2CO3 sample showed a relatively stable conductivity (7-9 Ã 10â2 S cmâ1) during a 650 h measurement under air at 600 °C. Single cell based on the composite electrolytes was reported for the first time, a maximum power density of 617 W cmâ2 and the open circuit voltage (OCV) of 1.01 V were achieved at 600 °C for the composite containing 20 wt% carbonates. The notable thermal stability together with fairly high performance emphasize the promise of LSGM-(Li/Na)2CO3 composite electrolytes for long-term LTSOFCs.
Related Topics
Physical Sciences and Engineering
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Electrochemistry
Authors
Fucheng Xie, Cheng Wang, Zongqiang Mao, Zhongliang Zhan,