| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7720543 | International Journal of Hydrogen Energy | 2014 | 7 Pages |
Abstract
An inverse CeO2/CuO catalyst has been investigated by operando steady-state isotopic transient kinetic analysis (SSITKA) in combination with diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) under 3% COÂ +Â 3% H2O reactant mixture at 473Â K with the aim of determining intermediates involved in the water-gas shift reaction at relatively low temperatures. Among the various species detected in the infrared spectra which may be involved in the reaction, i.e. formates, copper carbonyls and carbonates, a particular type of carbonate species is identified as a reaction intermediate on the basis of detailed analysis of the spectra during isotopic exchange in comparison with the change in the corresponding isotopically labelled CO2 product.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Electrochemistry
Authors
A. López Cámara, S. Chansai, C. Hardacre, A. MartÃnez-Arias,