Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7720548 | International Journal of Hydrogen Energy | 2014 | 10 Pages |
Abstract
Proton exchange membrane liquid water electrolyser operated blow 80 °C suffers from insufficient catalyst activity and durability due to the slow oxygen evolution kinetics and poor stability. Aiming at enhancing oxygen electrode kinetics and stability, composite materials consisting of antimony doped tin oxide and Cs-substituted phosphotungstate were synthesized as the support of iridium oxide and possessed functionality of mixed electronic and protonic conductivity. At 80 °C under dry ambient atmosphere, the materials showed an overall conductivity of 0.33 S cmâ1. The supported IrO2 catalysts were characterized in sulfuric acid electrolyte, showing significant enhancement of the oxygen evolution reaction (OER) activity. Electrolyser tests of the catalysts were conducted at 80 °C with a Nafion membrane. At an IrO2 loading of 0.75 mg cmâ2 and a Pt loading of 0.2 mg cmâ2, the cell performance of a current density of 2 A cmâ2 at 1.66 V was achieved. The cell showed good durability at 35 °C under a current density of 300 mA cmâ2 in a period of 464 h.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Electrochemistry
Authors
Gaoyang Liu, Junyuan Xu, Juming Jiang, Bingshuang Peng, Xindong Wang,