Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7720837 | International Journal of Hydrogen Energy | 2014 | 9 Pages |
Abstract
Present work describes a kinetic analysis of various aspects of biohydrogen production in batch test using optimized conditions obtained previously. Monod model and Logistic equation have been used to find growth kinetic parameters in batch test under uncontrolled pH. The values of μm, Ks, and Xm were 0.64 hâ1, 15.89 g-COD Lâ1, and 7.26 g-VSS Lâ1, respectively. Modified Leudeking-Piret and Michaelis-Menten equation corroborates a flux of energy to hydrogen production pathway and energy sufficiency in the system. Modified Gompertz equation illustrates that the overall rate and hydrogen yield at 15 g-COD Lâ1 was higher compared to a dark fermentation of other wastewaters. Besides, Andrew's equation also suggests that since the higher value of KI (19.95 g-COD Lâ1), k (255 mL hâ1 Lâ1) was not inhibited at high S. The experimental results implied that the entire products during the fermentation process were growth and substrate degradation associated. The result also confirms that the acetate and butyrate were substantially used for hydrogen production in acidogenic metabolism under uncontrolled pH.
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Authors
Abhijit Gadhe, Shriram S. Sonawane, Mahesh N. Varma,