Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7721015 | International Journal of Hydrogen Energy | 2013 | 12 Pages |
Abstract
Hydrotalcite-derived Ru catalysts were tested in the catalytic partial oxidation of CH4 to produce syngas. The effect of Ru content, oxidic matrix composition, and preparation procedure on chemical-physical properties and performances of catalysts was studied. Bulk catalysts (0.25 and 0.50 wt.% Ru) were obtained via Ru/Mg/Al hydrotalcite-type (HT) precursors with carbonates or silicates as interlayer anions. A supported catalyst was prepared by impregnation on a calcined Mg/Al-CO3 HT. Ru/γ-Al2O3 was evaluated for comparison. Both the Ru dispersion and the interaction with the support decreased as the Ru loading increased and when silicates were present due to RuO2 segregation. Regardless of the Ru loading, carbonate-derived catalysts performed better than those containing silicates. The increased Ru loading improved the initial activity, but deactivation occurred after high temperature tests. Stability tests for shorter contact times over a 0.25 wt.% bulk sample obtained from Ru/Mg/Al HT with carbonates showed a tendency to deactivate at 750 °C.
Related Topics
Physical Sciences and Engineering
Chemistry
Electrochemistry
Authors
Adriana Ballarini, Patricia Benito, Giuseppe Fornasari, Osvaldo Scelza, Angelo Vaccari,