Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7721489 | International Journal of Hydrogen Energy | 2013 | 9 Pages |
Abstract
AuNi nanoparticles supported on the activated carbon (AuNi/C) are synthesized by the impregnation method in the ethyleneglycol system using NH2NH2·H2O as a reducing agent. The alloying of Au and Ni and the removal of unalloyed Ni in the AuNi/C composition are achieved by heat and acid treatments in sequence. Research results reveal that the average size and alloying degree of the AuNi nanoparticles in the AuNi/C catalyst increase with the enhancement of the annealing temperature. However, the Ni content of the AuNi/C catalyst firstly goes up and then down with the rising of heat treatment temperature due to the AuNi system phase-separates. Moreover, the electrocatalytic activity normalized by the electrochemically active surface area of each AuNi/C catalyst is far better than that of the Au/C catalyst, because of the bifunctional mechanism and the electrocatalytic activity of the NiOOH. In particular, the AuNi/C catalyst annealed at 400 °C exhibits the most excellent activity, due to its small AuNi particles and proper alloying degree. Furthermore, its mass-specific electrochemical activity is higher than that of the Au/C catalyst, although the mean diameter of the AuNi nanoparticles in this catalyst is larger than that of the Au nanoparticles.
Related Topics
Physical Sciences and Engineering
Chemistry
Electrochemistry
Authors
Shaohui Yan, Lizhen Gao, Shichao Zhang, LiLi Gao, Weike Zhang, Yuzhen Li,