Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7723120 | International Journal of Hydrogen Energy | 2013 | 7 Pages |
Abstract
Nano-sized BaCe0.8Sm0.2O3âδ and Cu-doped BaCe0.8Sm0.2O3âδ proton conducting electrolyte powders are synthesized by citric-nitrate method, and then the powder properties are investigated. The synthesized BaCe0.8Sm0.2O3âδ powder acquires pure perovskite structure after heat treatment above 1100 °C, while impurity phases such as BaCO3 and Ce0.8Sm0.2O2âδ are formed below 1100 °C. The BaCe0.8Sm0.2O3âδ and Cu-doped BaCe0.8Sm0.2O3âδ showed similar powder characteristics, except the shrinkage rate. The sintering temperature for densification of the synthesized BCS are significantly reduced as much as â¼300 °C by small amount of Cu. Compared to drastic reduction in sintering temperature, the total conductivity and the activation energy of Cu doped BCS turn out to deviate negligibly from those of pure BCS.
Related Topics
Physical Sciences and Engineering
Chemistry
Electrochemistry
Authors
Inyu Park, Jeongin Kim, Jinyi Choi, Hunhyeong Lee, Jonghun Park, Dongwook Shin,