Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
77346 | Microporous and Mesoporous Materials | 2007 | 6 Pages |
Abstract
Rietveld analysis of synchrotron powder X-ray diffraction data obtained from the product of the reaction of cadmium vapour with dehydrated zinc-exchanged zeolite A (LTA structure type) indicates the formation of cationic zinc–cadmium alloy clusters. The clusters are located in approximately 40% of the sodalite cages; the remaining 60% of the cages contain divalent zinc ions coordinated both to the oxygen atoms of the zeolite framework and to residual extra framework oxygen.
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Physical Sciences and Engineering
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Authors
Jennifer E. Readman, Ian Gameson, Joseph A. Hriljac, Paul A. Anderson,