| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7762718 | Polyhedron | 2018 | 5 Pages |
Abstract
The 10-vertex Manganese-decaborane [nido-6-Mn(CO)3B9H13][NMe4] was found to act as an efficient catalyst for isocyanate cyclodimerization under photo-irradiation conditions. The reaction yields were comparable with other metal catalyst reported in literature. One of the products was characterized by X-ray crystallographic study and reaction mechanism was also proposed. The results are very encouraging as they represent first examples of a large metallaborane compound to catalyze the cyclodimerization of isocyanates.30
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Pei Ma, James T. Spencer,