Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7764552 | Polyhedron | 2016 | 25 Pages |
Abstract
Two linkage isomers, [(μ2-(p-toluenethiolato))2Fe2(CO)6] (1) and [(μ2-(α-toluenethiolato))2Fe2(CO)6] (2) have been prepared in moderate yields. The composition and structure of the compounds were ascertained by elemental analysis, NMR spectroscopy and X-ray diffraction. Comparatively, compound 1 electrochemical reduces proton to hydrogen at an overpotential 90 mV lower than compound 2.51
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Adrian L. Haley, Lauren N. Broadbent, Lindsey S. McDaniel, Skye T. Heckman, Carlee H. Hinkle, Nikolay N. Gerasimchuk, John C. Hershberger, Charles A. Mebi,