Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7764559 | Polyhedron | 2016 | 5 Pages |
Abstract
The reactivity of the anti-aromatic pentaphenylborole with HBpin (pinacolborane), HGeEt3, and HSnBu3 was investigated. In all cases the products were 1-bora-cyclopent-3-ene heterocycles resulting from the stereospecific addition of the E-H bond to the borole. Both HGeEt3, and HSnBu3 furnished syn products, while the reaction with pinacolborane yielded the anti product.31
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Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Ben C. Caputo, Zackery J. Manning, Jonathan H. Barnard, Caleb D. Martin,