Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7764577 | Polyhedron | 2016 | 39 Pages |
Abstract
Iron dibromide complexes bearing α-diimine ligands ArNC(Me)(Me)CNAr and ArBIAN (BIAN = bis(imino)acenaphthene; Ar = dpp and Mes; dpp = 2,6-diisopropylphenyl; Mes = 2,4,6-trimethylphenyl) are prepared and promote the catalytic hydrosilylation of 1-hexene. A high-spin iron(II) precatalyst and a redox-active [dppBIAN1â]FeI catalyst electronic structure description is supported by computational analysis.69
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Michael J. Supej, Alexander Volkov, Louisa Darko, Ryan A. West, Jonathan M. Darmon, Charles E. Schulz, Kraig A. Wheeler, Helen M. Hoyt,