Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7764582 | Polyhedron | 2016 | 8 Pages |
Abstract
The synthesis and characterization of a series of complexes based upon a central tripalladium ditropylium (Tr) unit [Pd3Tr2]2+ containing different nitrogen-based ligands is reported. The complexes were synthesized in good yield and characterized by multi-nuclei NMR spectroscopy, elemental microanalysis and single-crystal X-ray crystallography. Variation in the equatorial ligand strongly influences PdN bond distances, but has only a minor effect on PdPd distances.58
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
John C. Charbonneau, Cory B. Cluff, Hannah R. Babbini, Dominic C. Babbini, Gary S. Nichol, Stephanie K. Hurst,