Article ID Journal Published Year Pages File Type
7764602 Polyhedron 2016 18 Pages PDF
Abstract
Treatment of the in situ generated Me2NCSSeNa with (PPh3)2NiBr2 in degassed MeCN or THF gave a violet complex (PPh3)Ni(Br)(κ2S,Se-SSeCNMe2) (1). Attempts to crystalize the salt Me2NCSSeNa produced the dimeric compound (Me2NCSSe)2 (2). Complex 1 was characterized by 1H, 13C{1H}, 31P{1H} and 77Se NMR spectroscopy as well as mass spectrometry, elemental analysis and X-ray crystallography.39
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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