Article ID Journal Published Year Pages File Type
7764610 Polyhedron 2016 18 Pages PDF
Abstract
The bulky tertiary phosphane sulfide, SPBn3, reacts with Cu(I) to form 3-coordinate [Cu(CH3CN)(SPBn3)2]PF6 whereas with Ag(I) it forms dinuclear [Ag2(SPBn3)3](PF6)2 which contains both 3- and 4-coordinated Ag. The Ag atoms are linked by a bridging sulfur and a carbon from the aromatic ring of the same SPBn3.69
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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