Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7764610 | Polyhedron | 2016 | 18 Pages |
Abstract
The bulky tertiary phosphane sulfide, SPBn3, reacts with Cu(I) to form 3-coordinate [Cu(CH3CN)(SPBn3)2]PF6 whereas with Ag(I) it forms dinuclear [Ag2(SPBn3)3](PF6)2 which contains both 3- and 4-coordinated Ag. The Ag atoms are linked by a bridging sulfur and a carbon from the aromatic ring of the same SPBn3.69
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Eric W. Ainscough, Andrew M. Brodie, Graham H. Freeman, Paul G. Plieger,