Crystal structure of NaCd(H2PO3)3·H2O and spectroscopic study of NaM(H2PO3)3·H2O, M = Mn, Co, Ni, Zn, Mg and Cd

The paper is reporting on the new crystal structure of NaCd(H2PO3)3·H2O and spectroscopic study of NaM(H2PO3)3·H2O, M = Mn, Co, Ni, Zn, Mg and Cd. The crystal structure of NaCd(H2PO3)3·H2O is fully described. IR spectra of the whole series NaM(H2PO3)3·H2O, M = Mn, Co, Ni, Zn, Mg and Cd are reported. UV-Vis spectra from Mn, Co and Ni terms of the above mentioned series are discussed and d-d transitions have been assigned.97