Article ID Journal Published Year Pages File Type
7764729 Polyhedron 2015 35 Pages PDF
Abstract
A new ONSO donor azophenol ligand (HL) having thioether-S and ether-O atoms and its copper(II) complex have been synthesized and characterized. The hydrazoketo and azoenol equilibrium of the ligand has been studied by a theoretical study. The structure of the copper(II) complex, having the formula [Cu(L)(H2O)](ClO4), has been confirmed by a single crystal X-ray study. DFT calculations have been carried out to interpret the electronic structures and spectral properties of HL and its Cu(II) complex.231
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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