| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7764822 | Polyhedron | 2015 | 21 Pages |
Abstract
The ligand field effect and magnetostructural correlations in the family of pseudotetrahedral complexes [Co(qu)2X2] (qu = quinoline and X = NCSâ, Clâ, Brâ and Iâ) were analyzed. Compound [Co(qu)2Br2], which was missing in this row, was synthesized and characterized by single crystal X-ray analysis, SQUID measurements and Vis-NIR spectroscopy. Ab initio quantum-chemical calculations of the magnetic anisotropy parameter D and g-tensor were performed for all compounds in the family.84
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Authors
Denis V. Korchagin, Gennadii V. Shilov, Sergey M. Aldoshin, Roman B. Morgunov, Artem D. Talantsev, Elena A. Yureva,