| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7764897 | Polyhedron | 2015 | 8 Pages |
Abstract
The 1:1 reaction of cis-[PtCl2(dmso)2] with (E)-N,Nâ²-bis(2-pyridyl)iminoisoindoline (2-pyimiso) yielded [PtCl2(dmso-κS)(2-pyimiso-κN)] (1), in which 2-pyimiso coordinates to Pt(II) via the 2-pyridyl group attached to the imine nitrogen atom. Spectroscopic results showed that 1 was isolated as the trans-isomer. trans-1 is the most stable geometric isomer at the DFT M06/LACV3Pââ level of calculation.35
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![A contribution to the coordination chemistry of (E)-N,Nâ²-bis(2-pyridyl)iminoisoindoline (2-pyimiso): Synthesis, characterization, and DFT calculations of trans-[PtCl2(dmso-κS)(2-pyimiso-κN)]](/preview/png/7764897.png "First Page Preview: A contribution to the coordination chemistry of (E)-N,Nâ²-bis(2-pyridyl)iminoisoindoline (2-pyimiso): Synthesis, characterization, and DFT calculations of trans-[PtCl2(dmso-κS)(2-pyimiso-κN)]")
Authors
Rodrigo S. Bitzer, Marco A.C. Nascimento, Carlos A.L. Filgueiras,