| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7764919 | Polyhedron | 2015 | 8 Pages |
Abstract
Two novel oxomolybdenum(V)-trispyrazolylborate complexes [(TpMoO)(μ2-O)2(MoOTp)](Tp = tris(pyrazolyl)borate) (1) and [(Tp4IMoOCl)(μ-O)(MoOClTp4I)](Tp4I = tris(4-iodinpyrazolyl)borate) (2) were synthesized and characterized by elemental analysis, IR spectra and single-crystal X-ray diffraction. Their catalytic performances in cyclohexane (Cy) oxidation were studied. It is found that the catalytic performances of molybdenum(V) complexes 1 and 2 were far more better than the molybdenum(VI) complexes with the similar structure. The influence of the amount of H2O2, HNO3 and the solvents on the Cy oxidation were investigated too.138
Related Topics
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Inorganic Chemistry
Authors
Xin Liu, Na Xing, Jian Song, Qiong Wu, Zhidan Yan, Yan Zhang, Yongheng Xing,