Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7765033 | Polyhedron | 2015 | 9 Pages |
Abstract
Three complexes of dimethyl pyridine-2,6-dicarboxylate (MPC) including [Hg(MPC)Cl2] (1), [Cd(MPC)3][CdBr4] (2) and a coordination polymer, {K[Cr(PDC)2]}n (3) were prepared and identified by elemental analysis, FT-IR, Raman, 1H NMR spectroscopies and single-crystal X-ray diffraction. All coordination modes of MPC derivatives were studied by CSD and then optimized by DFT. A new formula for determination of geometry around the metals with coordination number four is presented.180
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Mohammad Hakimi, Zahra Mardani, Keyvan Moeini, Fabian Mohr,