| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7765251 | Polyhedron | 2015 | 13 Pages |
Abstract
Three series 5-Z-2-Br-isophthalaldimines were treated with Pd2(dba)3 to afford the corresponding pincer complexes. Sonogashira coupling demonstrated that the PdII-NCN-NO2 pincers normally exhibited a higher catalytic activity than PdII-NCN-But, PdII-NCN-H pincers. The structural comparison indicated that the both the group NO2 at the position-4 of palladium (II) and Me group at the aniline ring might be responsible for the pincers' high activity, particular for the former dominated.
Related Topics
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Authors
Jin-Hua Zhang, Ping Li, Wen-Ping Hu, Hong-Xing Wang,