| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7765368 | Polyhedron | 2015 | 9 Pages |
Abstract
A unique PdII complex with metal-metal (d8-d8) bonding interaction, [Pd(pic)(cbdca)]2·H2O (pic = 2-aminomethylpyridine and cbdca2â = cyclobutane-1,1-dicarboxylate) has been synthesised and characterized by spectroscopic methods. Density Functional Theory (DFT) study shows PdII-PdII bond distance of 3.18 Ã
in the complex which is close to the observed distance of 3.1790(1)Â Ã
found from X-ray crystal structure.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Ishani Mitra, Goutam Kr. Ghosh, Subhajit Mukherjee, Venkata P. Reddy B., Wolfgang Linert, Frank Kubel, Xavier Rocquefelte, Sankar Ch. Moi,