| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7765382 | Polyhedron | 2015 | 6 Pages |
Abstract
The structure of a diphenyl(2-pyridyl)phosphine oxide uranyl nitrate compound shows a monodentate mode of bonding for the ligand through the phosphine oxide oxygen atom to the uranyl group. The pyridyl nitrogen atom is uncoordinated. Theoretical studies reveal that the 2:1 complex with two monodentate phosphine oxide ligands with uranyl nitrate is more stable than the corresponding 1:1 complex with one chelating bidentate phosphine oxide ligand by 13.5Â kcal/mol.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Bal Govind Vats, S. Kannan, K. Parvathi, D.K. Maity, M.G.B. Drew,