| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7765714 | Polyhedron | 2014 | 8 Pages |
Abstract
The Nb(III) complex (BDI)Nb(NtBu)(CO)2 reacts with two equivalents of t-butylacetylene to form a metal-bound yne-one-ene moiety resulting from coupling of CO to two equivalents of the terminal alkyne. Additionally, Z-alkene and α,β-unsaturated imine formation from hydrogenolysis of an internal alkyne bound complex in the presence of an isocyanide ligand is described. 65
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Thomas L. Gianetti, Robert G. Bergman, John Arnold,