Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7765719 | Polyhedron | 2015 | 6 Pages |
Abstract
The electrical properties of a new molecular-ionic complex [C6H18N2]2 SbCl5 Cl2 were studied in the temperature range 293Â K-418Â K. The internal dynamics of protons of [C6H18N2] SbCl5 [C6H17N2] Cl2 were studied by 1H NMR method. Below 393Â K the Grotthus type mechanism of proton transport models the conductivity of studied [C6H17N2] SbCl5 [C6H17N2] Cl2 crystal i.e. diffusion of protons and turn of the cation around the pseudo C3 axis take place. The favoured type of conductivity in complex under study is the protonic ones.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
K. Holderna-Natkaniec, M. Ouled Mohamed Sghaier, P. Åawniczak, M. Zdanowska-FrÄ
czek, A. Wozniak-Braszak, S. Chaabouni,