Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7765722 | Polyhedron | 2014 | 26 Pages |
Abstract
Rhodium(I) and Iridium(I) borate complexes [Me2B(2-py)2]ML2 (L2Â =Â (tBuNC)2, (CO)2, (C2H4)2, cod, dppe) have a boat-configured chelate ring that participates in a boat-to-boat ring flip. The barrier of this ring flip is correlated to the Ï acceptor ability of the ancillary ligand groups on the metal.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Megan K. Pennington-Boggio, Brian L. Conley, Michael G. Richmond, Travis J. Williams,