| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7765749 | Polyhedron | 2014 | 8 Pages |
Abstract
We report here the first monomeric oxygen ligated d4 MoII complexes which are supported by two acetylacetonate or tropolonate ligands. Alkyne and phosphine complexes (LX)2Mo(CO)(RCCR) and (LX)2Mo(CO)2(PPh3) have been characterized. The alkyne compounds undergo exchange reactions with alkyne and phosphite ligands as well as oxidation to d2 MoIV oxo species.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Joseph Becica, Andrew B. Jackson, Brian M. Koronkiewicz, Nicholas A. Piro, W. Scott Kassel, Nathan M. West,